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Showing 375 results for Co

K. Ghanbari Ahari,
Volume 5, Issue 1 (3-2008)
Abstract

Abstract: Thermodynamic computational packages MTDATA and FactSage have been used to carry out calculations on the variation with temperature of the phases precipitated on cooling in both oxidising and reducing conditions of a typical ladle slag composition, in the temperature range 1700 - 900°C. The current coverage of the databases associated with the computational packages is discussed in relation to their application to slag - refractory interaction and the validity of the results is compared with some relevant experimental data and phase equilibrium studies
M. Kazemi Pour, S. Sharafi,
Volume 5, Issue 1 (3-2008)
Abstract

Abstract: Hardfacing is one of the most useful and economical ways to increase the service life of components subjected to abrasive wear. Iron based hardfacing alloys have long been considered as candidate coatings for wear-resistant applications in industry. In the present work two layer of Fe-34Cr-4.5C%wt hardfacing alloy was deposited on ASTM A36 carbon steel plates by SMAW method. The microstructure consists of large primary and eutectic M7C3 carbides, metastable austenite and small amount of secondary carbides. The microstructure was analyzed by optical and scanning electron microscopes. In the same condition of size, shape, distribution and volume fraction of carbides the as-welded matrix changed to martensite, tempered martensite and ferrite by heat treatment processes. The wear resistance was measured by pin-on-disk method under loads of 5, 10 and 20N and for sliding distance of 1500m. The results showed that the as-welded sample with austenitic matrix has the most and the ferritic matrix specimen has the least wear resistance. The predominate mechanisms for mass losses were determined to be micro-cutting, microploughing.
C. Dehghanian, Y. Mirabolfathi Nejad,
Volume 5, Issue 1 (3-2008)
Abstract

Abstract: Despite having a number of advantages, reinforced concrete can suffer rebar corrosion in high–chloride media, resulting in failure of reinforced concrete structures. In this research the corrosion inhibition capability of the mixture of calcium and ammonium nitrate of steel rebar corrosion was investigated in the simulated concrete pore solution. Cyclic polarization and Electrochemical Impedance Spectroscopy (EIS) techniques were applied on steel concrete pore solution containing 2 weight percent sodium chloride (NaCl). Results show that such mixtures had higher inhibition efficiency than calcium nitrate alone. The optimum concentration of the inhibitor mixture was determined to be 45 mgr/lit.
A. Allahverdi, E. Najafi Kani, S. Esmaeilpoor,
Volume 5, Issue 2 (6-2008)
Abstract

Abstract: The use of alkali-activated cementitious materials especially over the past decades has significantly been increased. The goal of this research is to investigate the effects of silica modulus and alkali concentration on alkali-activation of blast-furnace slag. In this research, the most important physical characteristics of cementitious systems, i.e. the 28-day compressive strength and final setting time, were studied by changing influencing parameters such as silica modulus, i.e. SiO2/Na2O, (0.44, 0.52, 0.60, and 0.68) and Na2O concentration (4, 6, 8 and 10% by weight of dry binder) at a constant water-to-dry binder ratio of 0.25. Final setting time of the studied systems varies in the range between 55-386 minutes. The obtained results show that systems cured at an atmosphere of more than 95% relative humidity at room temperature exhibit relatively high 28-day compressive strengths up to 107 MPa.
A. Moosavi, A. Aghaei,
Volume 5, Issue 2 (6-2008)
Abstract

Abstract: Auto-ignited gel combustion process has been used for producing a red hematite-zircon based pigment. The combustible mixtures contained the metal nitrates and citric acid as oxidizers and fuel, respectively. Sodium silicate (water glass) was used as silica source for producing zircon phase. X-Ray Diffractometery, Electron Microscopy and Simultaneous Thermal Analysis were used for characterization of reactions happened in the resulted dried gel during its heat-treatment. L* a* b* color parameters were measured by the CIE (Commission International de I'Eclairage) colorimetric method. This research has showed that solution combustion was unable to produce coral pigment as the end product of combustion without the need for any further heat treatment process.
M. Divandari,, H. Arabi, H. Ghasemi Mianaei,
Volume 5, Issue 3 (9-2008)
Abstract

Abstract: Thermal fatigue is a stochastic process often showing considerable scatter even in controlled environments. Due to complexity of thermal fatigue, there is no a complete analytical solution for predicting the effect of this property on the life of various components, subjected to severe thermal fluctuations. Among these components, one can mention car cylinder, cylinder head and piston which bear damages due to thermal fatigue. All these components are usually produced by casting techniques. In order to comprehend and compare the thermal fatigue resistance of cast Al alloys 356 and 413, this research was designed and performed. For this purpose, several samples in the form of disc were cast from the two alloys in sand mould. The microstructures of the cast samples were studied by light microscopy in order to choose the samples with the least amounts of defects for thermal fatigue tests. The results of thermal fatigue tests showed that the nucleation of microcracks in Al-356 alloy occurred at shorter time relative to those occurred in Al- 413 alloy under the same test conditions. In addition, the density of micro-cracks in Al-356 alloy was more than that of Al-413 alloy. The results of fractography on 356 alloy indicated that the cracks were generally nucleated from inter-dendritic shrinkage porosities and occasionally from the interface of silicon particles with the matrix. The growth of these micro cracks was along the dendrite arms. Fractography of 413 alloy fracture surfaces showed that nucleation of microcracks was often associated with silicon particles.
H. Naffakh,, M. Shamanian, F. Ashrafizadeh,
Volume 5, Issue 3 (9-2008)
Abstract

Abstract: The investigation is carried out to characterize welding of AISI 310 austenitic stainless steel to Inconel 657 nickel-chromium superalloy. The welds were produced using four types of filler materials: the nickel-based corresponding to Inconel 82, Inconel A, Inconel 617 and austenitic stainless steel 310. This paper describes the effects of aging treatment on the joint. The comparative evaluation was based on microstructural features and estimation of mechanical properties. While Inconel A exhibited highest thermal stability and mechanical properties (hardness and ultimate strength), Inconel 82 weld metal also showed good thermal stability and mechanical properties. On the other hand, welds produced with Inconel 617 and 310 SS filler materials showed weak thermal stability and failed in the weld metals. It is therefore concluded that for the joint between Inconel 657 and 310 stainless steel, Inconel A and Inconel 82 filler materials offered the best compromises, respectively.
M. Ghalambaz, M. Shahmiri,
Volume 5, Issue 3 (9-2008)
Abstract

Abstract: Cooling slope-casting processing is a relatively new technique to produce semisolid cast feedstock for the thixoforming process. Simple equipment, ease of operation, and low processing costs are the main advantages of this process in comparison with existing processes such as mechanical stirring, electromagnetic stirring, etc. The processing parameters of cooling slope casting are length, angle and the material of the inclined plate and their combinations, which usually affect the micro structural evolutions of the primary solid phase. In order to clarify the effect of the processing parameters on the evolution of the particle size, based on experimental investigation, Artificial Neural Network (ANN) was applied to predict the primary silicon crystals (PSCs) size of semisolid cast ingot via a cooling slope casting process of Al-20%(wt.%) Si alloy. The results demonstrated that the ANN, with 2 hidden layers and topology (4, 3), could predict the primary particle size with a high accuracy of 94%. The sensitivity analysis also revealed that material of the cooling slope had the largest effect on particle size.
M. Keyanpour-Rad, S. Keyanpour-Rad,
Volume 5, Issue 3 (9-2008)
Abstract

Abstract: A novel dust free alginate impression material was formulated and prepared, comprising an alginate polyvinylpyrrolidone and tetraflouroethylene resins, a mixture of liquid paraffin and dimethylpolysiloxane oil as the dust generation controlling agents and processed diatomaceous earth filler which was obtained from Iranian ore. No dusting was detected during the mixing of the powder and the conventional properties of the impression material, like working and setting times and compressive strength were in the range of the required specifications for alginate dental impressions. The compressive strength was measured to be 2.6 times of the minimum requirement for such fast setting impressions.
M. Farhani,, M. Soltanieh, M. R. Aboutalebi,
Volume 5, Issue 3 (9-2008)
Abstract

Abstract: Dissolution and recovery of Mn-Al compacts with and without a chloride flux was studied by taking samples from the melt after addition of the compact. Events occurring after the addition of the compacts into the melt were studied using water quenched specimens after holding them for a specified time in molten state. The cross sections of these specimens were characterized by SEM as well as optical imaging. The results showed that an optimized amount of flux (10 to 15%wt. in this research) considerably decreases the time to reach more than 90% recovery in comparison with non-fluxed compacts. The flux caused the intermetallic forming reactions to be started considerably sooner in fluxed compacts in comparison with the non-fluxed compact. Consequently, the incubation time decreased from about 180 seconds for non-fluxed compacts to less than 3 seconds for compacts with 10%wt. flux.
M. Shahmiri, S. Murphy,
Volume 5, Issue 4 (12-2008)
Abstract

Abstract: The microstructural features of the early stage of ordering of the intermetallic compound Pt2FeCu have been examined using optical and transmission electron microscopy in conjunction with X-ray diffraction technique. It was found that the compound has similar morphological alteration to that of FePt in which the ordering cannot be suppressed by rapid quenching. The early stage of ordering transformation was initiated at temperatures above the critical value of 1178 oC, by a homogeneous nucleation of the intermediate short range ordered particles and ultra rapid directional-induced heterogeneous growth (burst type). As the result of these combined mechanisms, twin –related ordered domains have been formed which in turn minimize the strains produced by ordering reaction in polycrystalline material. The individual grain was divided up by different sizes of twin-related ordered domain bonded with {101} habit planes.
M. Ghassemi Kakroudi,
Volume 5, Issue 4 (12-2008)
Abstract

Abstract: Refractory materials containing cordierite (2MgO.2Al2O3.5SiO2) and mullite (3Al2O3.2SiO2) are used as support in furnaces, because of their low thermal expansion properties which confer them a very good ability to thermal shock resistance. Composed of two phases presenting very different CTE (1.5–3×10-6 for cordierite and 4–6×10-6 K-1 for mullite), these materials can develop damage during thermal cycling due to internal stresses. The resulting network of microcracks is well known to improved thermal shock resistance of materials, since it usually involves a significant decrease in their elastic properties. This paper is devoted to the characterisation of the damage generated by this CTE mismatch, thanks to the application of a specific ultrasonic device at high temperature.
S. Kianfar,, S. H. Seyedein, M. R.aboutalebi,
Volume 5, Issue 4 (12-2008)
Abstract

Abstract: The horizontal continuous casting process has received a significant attention for near net shape casting of non ferrous metals and alloys. Numerical Simulation has been widely used for process design and optimization of continuous casting process. In the present study, a 3-dimensional heat flow model was developed to simulate the heat transfer and solidification in a horizontal billet continuous casting system in which the air gap formation and its effect on heat extraction rate from solidifying billet was also considered. In order to test the developed model, it was run to simulate the heat transfer and solidification for an industrial billet caster. The predicted temperature distribution within the mold and billet was compared with those measured on the industrial caster in which a good agreement was obtained. Finally, parametric studies were carried out by validated model to evaluate the effects of different parameters on solidification profile and temperature distribution within the model brass billet. The microstructure of cast billet was analyzed to determine the secondary dendrite arm spacing (SDAS) under different cooling conditions. Based on measured SDAS and predicted solidification rate a correlation between SDAS and cooling rate was proposed for continuously cast brass billet.
H. Shahmir, M. Nili Ahmadabadi, F. Naghdi,
Volume 5, Issue 4 (12-2008)
Abstract

Abstract: In the present study the effect of thermomechanical treatment (cold work and annealing) on the transformation behavior of NiTi shape memory alloys was studied. Differential scanning calorimetry was used to determine transformation temperature and its relation to precipitates and defects. Three alloys including Ti-50.3at.% Ni, Ti-50.5at.% Ni (reclamated orthodontic wires) and 50.6at.% Ni alloy were annealed at 673 K and 773 K for 30 and 60 min after 15% cold rolling. It was found that the transformation characteristics of these alloys are sensitive to annealing treatment and composition. The temperature range of transformation is broadened during cold working and after subsequent annealing, the intermediate phase was appeared. The peaks become sharper and close together on each cooling and heating cycle with increasing annealing temperature and time
J. Saaedi, H. Arabi, Sh. Mirdamadi, Th. W. Coyle,
Volume 5, Issue 4 (12-2008)
Abstract

Abstract: Two different coating microstructures of Ni-50Cr alloy were obtained on a stainless steel substrate by changing combustion characteristics of a high velocity oxy-fuel (HVOF) process and the size distribution of feed powder during coating process. Use of the finer feed powder and leaner fuel in oxygen/fuel ratio (i.e. using a ratio much less than stoichiometric ratio) led to formation of an extremely dense coating with high oxide content. Heat treating of this coating at 650ºC for 4 hours caused the formation of an intermetallic sigma phase having Cr7Ni3 stoichiometry. Formation of this phase has been reported occasionally in thin films not in thermal spray coatings, as reported for the first time in this research. In addition no sigma phase was detected in the HVOF as-deposited coating with low oxide content after heat treatment of the samples. Therefore, due to the limited number of papers available in the subject of formation of phase in either Ni-Cr bulk alloys or coatings, it is considered appropriate to show up a case in this field. In this work, the formation of sigma phase in Ni-50Cr coating deposited by HVOF technique and heat treated at 650ºC was discussed and then the coating was characterized.
A.nouri, Sh.kheirandish, H. Saghafian,
Volume 5, Issue 4 (12-2008)
Abstract

Abstract: In the current work, the strain hardening behavior of dual-phase steels with different silicon content (0.34- 2.26 Wt. %) was examined using the modified Crussard-Jaoul analysis. It was shown that these dual-phase steels deform in two stages over a uniform strain range. Each stage exhibited a different strain hardening exponent varying with silicon content. At the first stage, work hardening exponent remind significantly constant, while during the second stage, it decreased with increasing silicon content from 0.34% to 1.51% and then increased for the higher silicon contents (1.51% to 2.26%). It was found that the strain hardening behavior of these steels was predominantly affected by the volume fraction of martensite at low silicon contet and the ferrite strengthening induced by silicon at the higher silicon content. The effect of silicon content on the volume fraction of martensite and tensile properties were also considered.
S.h.r. Fatemi Nayeri, J. Vahdati Khaki, M. R. Aboutalebi,
Volume 6, Issue 1 (3-2009)
Abstract

Abstract:A combination of mechanical activation and Differential Thermal Analysis (DTA) together with X-Ray Diffraction (XRD), and various microstractural characterization techniques were used to evaluate the starting reaction in the combustion synthesis of TiC-Al2O3 composite in TiO2-Al-C system. The mechanical activation was performed on the mixtures of two components of TiO2/Al, Al/C and TiO2/C and then the third component was added according to the stoichiometric reaction for 3TiC+2Al2O3 composite formation. The powder mixtures were heated up to 1450 °C under Argon atmosphere at a heating rate of 10 °C/min. The combustion synthesis temperature was observed to decrease from 962 °C to 649 °C after milling of TiO2/Al mixture for 16 hr. On the contrary, the mechanical activation of Al/C and TiO2/C mixtures for 16 hr made the reaction temperature increase to 995 °C and 1024 °C, respectively. The decrease in reaction temperature as a result of milling the TiO2/Al mixture could be due to an increase of TiO2 and Al interface area as confirmed by TEM micrographs and XRD patterns of milled powder mixture. In addition, DTA experiments showed that for the sample in which TiO2 and Al were mechanically activated the reaction occurred at the temperature even lower than that of Al melting point.
S.r. Allahkaram, R. Shamani,
Volume 6, Issue 1 (3-2009)
Abstract

Abstract: Due to the expansion of high voltage Alternating Current (AC) power transmission lines and cathodically protected buried pipelines, it is becoming more and more difficult to construct them with enough safe distances between them. Thus, the pipelines are frequently exposed to induced AC interferences, which result in perturbation of Cathodic Protection (CP) due to AC corrosion. To study the above criterion, an experimental set up was used with coupons exposed to simulated soil solutions, while under both CP and AC induced condition for which an AC+DC power supply was utilized. The experiments were carried out in several simulated soil solutions corresponding to several soil samples collected from various regions along a buried pipeline with overhead parallel high voltage power transmission line. The results indicated that AC corrosion depends strongly on the composition of the soil.
I. Ebrahimzadeh, Gh.h. Akbari,
Volume 6, Issue 1 (3-2009)
Abstract

Abstract: Horizontal continuous casting is widely used to produce semi-finished and finished metallic products. Homogeneity in metallurgical characteristics and mechanical properties in such products is of importance. In the present work microstructure and mechanical properties of a horizontal continuous cast pipe have been studied. Microstructural features were investigated by an optical microscope equipped with image analyzer and SEM was used to characterize precipitates. Tensile behavior, impact strength and hardness variations were the mechanical properties which were studied. Results showed that microstructure and mechanical properties had diversities in different parts of the pipe and distinct differences were observed between upper and lower parts of the pipe. A meaningful correlation was found in microstructure and mechanical properties in different parts of the component.
S.r. Allahkaram, R. Shamani,
Volume 6, Issue 2 (6-2009)
Abstract

Abstract: The risks of alternating current (AC) corrosion and overprotection increasingly demand new criteria for
cathodically protected pipelines. To assess the risk of AC corrosion, new cathodic protection (CP) criteria have been
proposed based on DC/AC current densities measurements using coupons. The monitoring system designed for this
project was based on the instant-off method, with steel coupons simulating coating defects on a buried pipeline. The
problems associated with the instantaneous off-potential measurements have been attributed to a non-sufficient time
resolution. In present study, it has been possible to determine the de-polarisation of steel coupon within a few
milliseconds after disconnecting the coupon from the DC/AC power source, by increasing data acquisition rate. For
this, a monitoring system was developed in order to measure the IR-free potential together with the DC/AC current
densities. The monitoring system was utilized for both laboratory experiments and site survey to study the mechanism
and the condition of AC corrosion, its mitigation and more importantly to define new CP criteria.



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