Abstract: (143 Views)
In this research, the morphology of the Ni-W coating was modified by adding graphene oxide (GO) nanosheets in such a way that a foam-like structure with high porosity and holes in the form of intertwined tunnels was obtained. Different amounts of GO nanosheets were added to the plating bath and the resulting coating was examined. In order to estimate the electrochemically active surface area, the cyclic voltammetry (CV) test was used. Moreover, the linear polarization test (LSV) and chronoamperometry in 1 M NaOH were conducted to investigate the electrocatalytic activity for the hydrogen evolution reaction (HER). It was found that by adding 0.4 g/L GO to the electroplating bath, the electrocatalytic properties are doubled and the active surface of the electrode is significantly increased.
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• Newfound foam-like Nickel-Tungsten/Graphene oxide coating as a catalyst for hydrogen evolution reaction (HER) with different content of graphene oxide was synthesized.
• By increasing the amount of GO nanosheets in the coating and enhancing the porosity, the electrochemically active surface area increased more than 10 times.
• The FTIR analysis reveals that GO is reduced during electroplating.
• Composite with a content of 0.4 g/L graphene oxide has the highest catalytic activity.